Ion-molecule reactions in isopropanol: Implications for its radiolysis
نویسندگان
چکیده
منابع مشابه
lon-Molecule Reactions in Isopropanol: Implications for Its Radiolysis *
The photoionization of isopropanol (i-PrO H) at 11.7 e V has been investigated in the NBS high pressure photoionization mass spectrometer over the pressure range 0.1 to approximately 200 millitorr_ The major primary ion, CHaCHOH+, reacts with a total rate coefficient of 1.1 ± 0_1 X 109 cma/molecule-s to yie ld mainly (i-PrOH)H+ and CH3(i-Ca H,)COH+ _ At pressures in excess of a few millitorr co...
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A point charge interacting with a dipole (either induced or permanent) constitutes a completely integrable dynamical subsystem characterized by three first integrals of the motion (E, p(phi), and either l(2) or a Hamilton-Jacobi separation constant beta). An ion-molecule reaction (capture or fragmentation) can be seen as an interaction between such a subsystem and a bath of oscillators. This in...
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ژورنال
عنوان ژورنال: Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
سال: 1972
ISSN: 0022-4332
DOI: 10.6028/jres.076a.057